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Electron Spin Resonance Spectra of Polymer Radicals in Aqueous Solution

Mixing of aqueous polymer solutions containing Ti(3+) and H(2)O(2) in a rapid flow mixer produced radicals by abstraction, OH + RH → R · + H(2)O, which were observed by electron spin resonance. Oscillation of segments was sufficient to narrow the lines to 0.5–2.0 g. Polymers and radicals identified...

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Veröffentlicht in:J Res Natl Bur Stand A Phys Chem
Hauptverfasser: Florin, Roland E., Sicilio, Fred, Wall, Leo A.
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Institute of Standards and Technology 1968
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6640580/
https://ncbi.nlm.nih.gov/pubmed/31824076
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.072A.006
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