Highly atroposelective synthesis of nonbiaryl naphthalene-1,2-diamine N-C atropisomers through direct enantioselective C-H amination

Nonbiaryl N-C atropisomer is an important structural scaffold, which is present in natural products, medicines and chiral ligands. However the direct enantioselective C-H amination to access optically pure N-C atropisomer is still difficult and rare. Here we report a π-π interaction and dual H-bond...

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Publicado no:Nat Commun
Main Authors: Bai, He-Yuan, Tan, Fu-Xin, Liu, Tuan-Qing, Zhu, Guo-Dong, Tian, Jin-Miao, Ding, Tong-Mei, Chen, Zhi-Min, Zhang, Shu-Yu
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6624262/
https://ncbi.nlm.nih.gov/pubmed/31296850
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-10858-x
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