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Site-specific hydrogen-atom elimination in photoexcited ethyl radical

The photochemistry of the ethyl radical following excitation to the 3p Rydberg state is investigated in a joint experimental and theoretical study. Velocity map images for hydrogen atoms detected from photoexcited isotopologues CH(3)CH(2), CH(3)CD(2) and CD(3)CH(2) at ∼201 nm, are discussed along wi...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Chicharro, David V., Poullain, Sonia Marggi, Zanchet, Alexandre, Bouallagui, Aymen, García-Vela, Alberto, Senent, María L., Rubio-Lago, Luis, Bañares, Luis
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6610558/
https://ncbi.nlm.nih.gov/pubmed/31341601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02140j
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