A vinyl silylsilylene and its activation of strong homo- and heteroatomic bonds

The facile synthesis of a rare two-coordinate acyclic silylene (R(2)Si:) that is stabilized using a bulky vinylic N-heterocyclic olefin ligand and the strongly σ-donating hypersilyl group [Si(SiMe(3))(3)](–) is reported. This vinyl-substituted silylene exhibits an excellent combination of prolonged...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Roy, Matthew M. D., Ferguson, Michael J., McDonald, Robert, Zhou, Yuqiao, Rivard, Eric
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2019
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6610552/
https://ncbi.nlm.nih.gov/pubmed/31341599
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01192g
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