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Acid-Base Behavior in 50-Percent Aqueous Methanol: Thermodynamics of the Dissociation of Protonated Tris(hydroxymethyl)aminomethane and Nature of the Solvent Effect

Electromotive-force methods and cells without liquid junction have been utilized to determine the acidic dissociation constant of protonated tris(hydroxymethyl)aminornethane [2-amino-2-(hydroxymethyl)-1, 3-propanediol] in 50 wt percent methanol solvent at seven temperatures from 10 to 40 °C. The cha...

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Detalhes bibliográficos
Publicado no:J Res Natl Bur Stand A Phys Chem
Main Authors: Woodhead, Maurice, Paabo, Maya, Robinson, R. A., Bates, Roger G.
Formato: Artigo
Idioma:Inglês
Publicado em: National Institute of Standards and Technology 1965
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6610350/
https://ncbi.nlm.nih.gov/pubmed/31927838
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.6028/jres.069A.026
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