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Superelectrophilicity of 1,2-Azaborine: Formation of Xenon and Carbon Monoxide Adducts

The BN analogue of ortho-benzyne, 1,2-azaborine, is shown to bind carbon monoxide and a xenon atom under matrix isolation conditions, demonstrating its strongly Lewis acidic superelectrophilic nature. The Lewis acid–base complexes involving CO and Xe can be cleaved photochemically and reformed by mi...

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Autores principales: Edel, Klara, Ishibashi, Jacob S. A., Liu, Shih-Yuan, Bettinger, Holger F.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2019
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6609157/
https://ncbi.nlm.nih.gov/pubmed/30786120
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813503
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