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Superelectrophilicity of 1,2-Azaborine: Formation of Xenon and Carbon Monoxide Adducts
The BN analogue of ortho-benzyne, 1,2-azaborine, is shown to bind carbon monoxide and a xenon atom under matrix isolation conditions, demonstrating its strongly Lewis acidic superelectrophilic nature. The Lewis acid–base complexes involving CO and Xe can be cleaved photochemically and reformed by mi...
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6609157/ https://ncbi.nlm.nih.gov/pubmed/30786120 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813503 |
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