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Decarboxylative Hydroalkylation of Alkynes

The merger of open- and closed-shell elementary organometallic steps has enabled the selective intermolecular addition of nucleophilic radicals to unactivated alkynes. A range of carboxylic acids can be subjected to a CO(2) extrusion, nickel capture, migratory insertion sequence with terminal and in...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Till, Nicholas A., Smith, Russell T., MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6607893/
https://ncbi.nlm.nih.gov/pubmed/29664294
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b02834
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