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Computational Kinetics by Variational Transition State Theory with Semiclassical Multidimensional Tunneling: Direct Dynamics Rate Constants for the Abstraction of H from CH(3)OH by Triplet Oxygen Atoms

Rate constants and the product branching ratio for hydrogen abstraction from CH(3)OH by O((3)P) were computed with multi-structural variational transition state theory including microcanonically optimized multi-dimensional tunneling. Benchmark calculations of the forward and reverse classical barrie...

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Xehetasun bibliografikoak
Argitaratua izan da:J Phys Chem A
Egile Nagusiak: Meana-Pañeda, Rubén, Xu, Xuefei, Ma, He, Truhlar, Donald G.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2017
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6594555/
https://ncbi.nlm.nih.gov/pubmed/28140597
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.6b10600
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