A New Mode of Chemical Reactivity for Metal‐Free Hydrogen Activation by Lewis Acidic Boranes

We herein explore whether tris(aryl)borane Lewis acids are capable of cleaving H(2) outside of the usual Lewis acid/base chemistry described by the concept of frustrated Lewis pairs (FLPs). Instead of a Lewis base we use a chemical reductant to generate stable radical anions of two highly hindered b...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Bennett, Elliot L., Lawrence, Elliot J., Blagg, Robin J., Mullen, Anna S., MacMillan, Fraser, Ehlers, Andreas W., Scott, Daniel J., Sapsford, Joshua S., Ashley, Andrew E., Wildgoose, Gregory G., Slootweg, J. Chris
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6594078/
https://ncbi.nlm.nih.gov/pubmed/30968535
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900861
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