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Catalytic protodeboronation of pinacol boronic esters: formal anti-Markovnikov hydromethylation of alkenes

Pinacol boronic esters are highly valuable building blocks in organic synthesis. In contrast to the many protocols available on the functionalizing deboronation of alkyl boronic esters, protodeboronation is not well developed. Herein we report catalytic protodeboronation of 1°, 2° and 3° alkyl boron...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Clausen, Florian, Kischkewitz, Marvin, Bergander, Klaus, Studer, Armido
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6585874/
https://ncbi.nlm.nih.gov/pubmed/31360428
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02067e
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