The Effect of pH and Biogenic Ligands on the Weathering of Chrysotile Asbestos: The Pivotal Role of Tetrahedral Fe in Dissolution Kinetics and Radical Formation

Chrysotile asbestos is a soil pollutant in many countries. It is a carcinogenic mineral, partly due to its surface chemistry. In chrysotile, Fe(II) and Fe(III) substitute Mg octahedra (Fe[6]), and Fe(III) substitutes Si tetrahedra (Fe[4]). Fe on fiber surfaces can generate hydroxyl radicals (HO(.))...

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Pubblicato in:Chemistry
Autori principali: Walter, Martin, Schenkeveld, Walter D. C., Reissner, Michael, Gille, Lars, Kraemer, Stephan M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6582442/
https://ncbi.nlm.nih.gov/pubmed/30417458
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201804319
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