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Laser- and cryogenic probe-assisted NMR enables hypersensitive analysis of biomolecules at submicromolar concentration

Solution-state NMR typically requires 100 μM to 1 mM samples. This limitation prevents applications to mass-limited and aggregation-prone target molecules. Photochemically induced dynamic nuclear polarization was adapted to data collection on low-concentration samples by radiofrequency gating, enabl...

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Veröffentlicht in:Proc Natl Acad Sci U S A
Hauptverfasser: Okuno, Yusuke, Mecha, Miranda F., Yang, Hanming, Zhu, Lingchao, Fry, Charles G., Cavagnero, Silvia
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 2019
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6575578/
https://ncbi.nlm.nih.gov/pubmed/31142651
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1820573116
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