Furanosyl Oxocarbenium Ion Conformational Energy Landscape Maps as a Tool to Study the Glycosylation Stereoselectivity of 2‐Azidofuranoses, 2‐Fluorofuranoses and Methyl Furanosyl Uronates

The 3D shape of glycosyl oxocarbenium ions determines their stability and reactivity and the stereochemical course of S(N)1 reactions taking place on these reactive intermediates is dictated by the conformation of these species. The nature and configuration of functional groups on the carbohydrate r...

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Dettagli Bibliografici
Pubblicato in:Chemistry
Autori principali: van der Vorm, Stefan, Hansen, Thomas, van Rijssel, Erwin R., Dekkers, Rolf, Madern, Jerre M., Overkleeft, Herman S., Filippov, Dmitri V., van der Marel, Gijsbert A., Codée, Jeroen D. C.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2019
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Full Papers
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6563709/
https://ncbi.nlm.nih.gov/pubmed/30882938
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201900651
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