N-Centered Chiral Self-Sorting and Supramolecular Helix of Tröger's Base-Based Dimeric Macrocycles in Crystalline State

Three stereoisomers of Tröger's Base-based dimeric macrocycles Trögerophane 1 (T1) including one pair of enantiomers (rac-T1) and one meso isomer (R(2N)S(2N)-T1) were obtained and fully characterized by X-ray analysis. In the crystalline stacking state R(2N)S(2N)-T1 showed heterochiral self-sor...

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Publicat a:Front Chem
Autors principals: Chen, Yuan, Cheng, Ming, Hong, Benkun, Zhao, Qian, Qian, Cheng, Jiang, Juli, Li, Shuhua, Lin, Chen, Wang, Leyong
Format: Artigo
Idioma:Inglês
Publicat: Frontiers Media S.A. 2019
Matèries:
Chemistry
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6555195/
https://ncbi.nlm.nih.gov/pubmed/31214566
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2019.00383
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