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Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H(2) formation with FeFe hydrogenase model complexes
Electron and proton transfer reactions of diiron complexes [Fe(2)adt(CO)(6)] (1) and [Fe(2)adt(CO)(4)(PMe(3))(2)] (4), with the biomimetic azadithiolate (adt) bridging ligand, have been investigated by real-time IR- and UV-vis-spectroscopic observation to elucidate the role of the adt-N as a potenti...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6552503/ https://ncbi.nlm.nih.gov/pubmed/31293742 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00876d |
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