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Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles

Selective in situ methylation of terminal chalcogenide ligands of molecular chalcogenido metalate anions in ionothermal reactions with alkylimidazolium-based ionic liquids yields a series of organo-functionalized chalcogenido metalate compounds. We present the syntheses and crystal structures of (C(...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Peters, Bertram, Santner, Silke, Donsbach, Carsten, Vöpel, Pascal, Smarsly, Bernd, Dehnen, Stefanie
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6540918/
https://ncbi.nlm.nih.gov/pubmed/31191876
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01358j
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