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Brønsted acid catalysis – the effect of 3,3′-substituents on the structural space and the stabilization of imine/phosphoric acid complexes

BINOL derived chiral phosphoric acids (CPAs) are widely known for their high selectivity. Numerous 3,3′-substituents are used for a variety of stereoselective reactions and theoretical models of their effects are provided. However, experimental data about the structural space of CPA complexes in sol...

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Publicat a:Chem Sci
Autors principals: Melikian, Maxime, Gramüller, Johannes, Hioe, Johnny, Greindl, Julian, Gschwind, Ruth M.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6540909/
https://ncbi.nlm.nih.gov/pubmed/31191877
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01044k
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