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Catalytic reduction of aryl trialkylammonium salts to aryl silanes and arenes
A new approach for the reduction of aryl ammonium salts to arenes or aryl silanes using nickel catalysis is reported. This method displays excellent ligand-controlled selectivity based on the N-heterocyclic carbene (NHC) ligand employed. Utilizing a large NHC in non-polar solvents generates aryl sil...
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| Gepubliceerd in: | Chem Sci |
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| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
Royal Society of Chemistry
2019
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6540906/ https://ncbi.nlm.nih.gov/pubmed/31191891 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01083a |
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