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High-Precision Electrochemical Measurements of the Guanine-, Mismatch-, and Length-Dependence of Electron Transfer from Electrode-Bound DNA Are Consistent with a Contact-Mediated Mechanism

Despite 25 years’ effort, serious questions remain regarding the mechanism(s) underlying electron transfer through (or from) electrode-bound double-stranded DNA. In part this is because a control experiment regarding the putatively critical role of guanine bases in the most widely proposed transport...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Dauphin-Ducharme, Philippe, Arroyo-Currás, Netzahualcóyotl, Plaxco, Kevin W.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6540082/
https://ncbi.nlm.nih.gov/pubmed/30605323
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11341
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