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Quantum Roaming in the Complex Forming Mechanism of the Reactions of OH with formaldehyde and methanol at Low Temperature and Zero Pressure: A Ring Polymer Molecular Dynamics Approach

The quantum dynamics of the title reactions are studied using the Ring Polymer Molecular Dynamics (RPMD) method from 20 to 1200 K using recently proposed full dimensional potential energy surfaces which include long range dipole-dipole interactions. A V-shaped dependence of the reaction rate constan...

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Detalhes bibliográficos
Publicado no:J Phys Chem Lett
Main Authors: del Mazo-Sevillano, Pablo, Aguado, Alfredo, Jiménez, Elena, Suleimanov, Yury V., Roncero, Octavio
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6534501/
https://ncbi.nlm.nih.gov/pubmed/30939028
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.9b00555
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