Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles

Catalytic carbonyl-olefin metathesis reactions have recently been developed as a powerful tool for carbon–carbon bond formation. However, currently available synthetic protocols rely exclusively on aryl ketone substrates while the corresponding aliphatic analogs remain elusive. We herein report the...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Albright, Haley, Riehl, Paul S., McAtee, Christopher C., Reid, Jolene P., Ludwig, Jacob R., Karp, Lindsey A., Zimmerman, Paul M., Sigman, Matthew S., Schindler, Corinna S.
Format: Artigo
Language:Inglês
Published: 2019
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6532644/
https://ncbi.nlm.nih.gov/pubmed/30596414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11840
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