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Photoredox/Nickel-Catalyzed Single-Electron Tsuji-Trost Reaction: Development and Mechanistic Insight

A regioselective, nickel-catalyzed photoredox allylation of secondary, benzyl, and α-alkoxy radical precursors is disclosed. Through this manifold, a variety of linear allylic alcohols and allylated monosaccharides are accessible in high yields under mild reaction conditions. Quantum mechanical calc...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Angew Chem Int Ed Engl
Prif Awduron: Matsui, Jennifer K., Gutiérrez-Bonet, Álvaro, Rotella, Madeline, Alam, Rauful, Gutierrez, Osvaldo, Molander, Gary A.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2018
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC6526374/
https://ncbi.nlm.nih.gov/pubmed/30307672
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201809919
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