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Threading-gated photochromism in [2]pseudorotaxanes

Rigid, Y-shaped imidazole compounds containing the bis(thienyl)ethene moiety were designed and synthesized. The 4,5-bis(benzothienyl)-2-phenylimidazolium cations were then used as axles for [2]pseudorotaxane formation with 24-membered crown ether wheels. It was demonstrated using (1)H NMR spectrosco...

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Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Baggi, Giorgio, Casimiro, Lorenzo, Baroncini, Massimo, Silvi, Serena, Credi, Alberto, Loeb, Stephen J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6524668/
https://ncbi.nlm.nih.gov/pubmed/31183062
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00913b
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