Controllable Isomerization of Alkenes by Dual Visible‐Light‐Cobalt Catalysis

We report herein that thermodynamic and kinetic isomerization of alkenes can be accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the ligand, the most stable isomers are obtained, while isomerizing terminal alkenes over one position can be selectively controll...

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Udgivet i:Angew Chem Int Ed Engl
Main Authors: Meng, Qing‐Yuan, Schirmer, Tobias E., Katou, Kousuke, König, Burkhard
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2019
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519376/
https://ncbi.nlm.nih.gov/pubmed/30835931
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900849
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