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Controllable Isomerization of Alkenes by Dual Visible‐Light‐Cobalt Catalysis

We report herein that thermodynamic and kinetic isomerization of alkenes can be accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the ligand, the most stable isomers are obtained, while isomerizing terminal alkenes over one position can be selectively controll...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Meng, Qing‐Yuan, Schirmer, Tobias E., Katou, Kousuke, König, Burkhard
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519376/
https://ncbi.nlm.nih.gov/pubmed/30835931
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900849
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