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Site‐Specific Oxidation State Assignments of the Iron Atoms in the [4Fe:4S](2+/1+/0) States of the Nitrogenase Fe‐Protein
The nitrogenase iron protein (Fe‐protein) contains an unusual [4Fe:4S] iron‐sulphur cluster that is stable in three oxidation states: 2+, 1+, and 0. Here, we use spatially resolved anomalous dispersion (SpReAD) refinement to determine oxidation assignments for the individual irons for each state. Ad...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6519357/ https://ncbi.nlm.nih.gov/pubmed/30698901 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813966 |
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