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Palladium-Catalyzed, Enantioselective Formal Cycloaddition between Benzyltriflamides and Allenes: Straightforward Access to Enantioenriched Isoquinolines
[Image: see text] Benzyl and allyltriflamides can engage in Pd-catalyzed oxidative (4+2) annulations with allenes, to produce highly valuable tetrahydroisoquinoline or dihydropyridine skeletons. The reaction is especially efficient when carried out in the presence of designed N-protected amino acids...
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| Veröffentlicht in: | J Am Chem Soc |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical
Society
2019
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6497426/ https://ncbi.nlm.nih.gov/pubmed/30636417 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12636 |
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