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Photoinitiated carbonyl-metathesis: deoxygenative reductive olefination of aromatic aldehydes via photoredox catalysis

Carbonyl–carbonyl olefination, known as McMurry reaction, represents a powerful strategy for the construction of olefins. However, catalytic variants that directly couple two carbonyl groups in a single reaction are less explored. Here, we report a photoredox-catalysis that uses B(2)pin(2) as termin...

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Publicat a:Chem Sci
Autors principals: Wang, Shun, Lokesh, Nanjundappa, Hioe, Johnny, Gschwind, Ruth M., König, Burkhard
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6492636/
https://ncbi.nlm.nih.gov/pubmed/31123568
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc00711c
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