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Synergic Deprotonation Generates Alkali‐Metal Salts of Tethered Fluorenide‐NHC Ligands Co‐Complexed to Alkali‐Metal Amides
Synergic combinations of alkali‐metal hydrocarbyl/amide reagents were used to synthesise saturated N‐heterocyclic carbene (NHC) ligands tethered to a fluorenide anion through deprotonation of a spirocyclic precursor, whereas conventional bases were not successful. The Li(2) derivatives displayed a b...
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| Udgivet i: | Chemistry |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6492165/ https://ncbi.nlm.nih.gov/pubmed/30667554 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201806278 |
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