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Water-Soluble Leaving Group Enables Hydrophobic Functionalization of RNA

Attachment of hydrophobic groups to RNA is challenging because of their poor aqueous solubility. One-step acylation of RNA 2′-OH groups in water using a water-soluble imidazole leaving group is described. The effect of the hydrophobic groups on hybridization is reported. Furthermore, propargyl-funct...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Org Lett
Hauptverfasser: Velema, Willem A., Kool, Eric T.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2018
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6478029/
https://ncbi.nlm.nih.gov/pubmed/30299958
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02938
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