Highly Linear Polyethylenes Achieved Using Thermo-Stable and Efficient Cobalt Precatalysts Bearing Carbocyclic-Fused NNN-Pincer Ligand

Six examples of 2-(1-arylimino)ethyl-9-arylimino-5,6,7,8-tetrahydrocycloheptapyridine-cobalt(II) chloride complexes, [2-(1-ArN)C(2)H(3)-9-ArN-5,6,7,8-C(5)H(8)C(5)H(3)N]CoCl(2), (Ar = 2-(C(5)H(9))-6-MeC(6)H(3) Co1, 2-(C(6)H(11))-6-MeC(6)H(3) Co2, 2-(C(8)H(15))-6-MeC(6)H(3) Co3, 2-(C(5)H(9))-4,6-Me(2)...

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Published in:Molecules
Main Authors: Guo, Jingjing, Wang, Zheng, Zhang, Wenjuan, Oleynik, Ivan I., Vignesh, Arumugam, Oleynik, Irina V., Hu, Xinquan, Sun, Yang, Sun, Wen-Hua
Format: Artigo
Language:Inglês
Published: MDPI 2019
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6471483/
https://ncbi.nlm.nih.gov/pubmed/30934627
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24061176
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