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Visible-Light-Driven Conversion of CO(2) to CH(4) with an Organic Sensitizer and an Iron Porphyrin Catalyst

Using a phenoxazine-based organic photosensitizer and an iron porphyrin molecular catalyst, we demonstrated photochemical reduction of CO(2) to CO and CH(4) with turnover numbers (TONs) of 149 and 29, respectively, under visible-light irradiation (λ > 435 nm) with a tertiary amine as sacrificial...

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Detalles Bibliográficos
Publicado en:J Am Chem Soc
Main Authors: Rao, Heng, Lim, Chern-Hooi, Bonin, Julien, Miyake, Garret M., Robert, Marc
Formato: Artigo
Idioma:Inglês
Publicado: 2018
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6467819/
https://ncbi.nlm.nih.gov/pubmed/30525556
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b09740
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