Off-stoichiometry improves the photostructuring of thiol–enes through diffusion-induced monomer depletion

Thiol–enes are a group of alternating copolymers with highly ordered networks and are used in a wide range of applications. Here, “click” chemistry photostructuring in off-stoichiometric thiol–enes is shown to induce microscale polymeric compositional gradients due to species diffusion between non-i...

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Detalhes bibliográficos
Publicado no:Microsyst Nanoeng
Main Authors: Hillmering, Mikael, Pardon, Gaspard, Vastesson, Alexander, Supekar, Omkar, Carlborg, Carl Fredrik, Brandner, Birgit D., van der Wijngaart, Wouter, Haraldsson, Tommy
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2016
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6444721/
https://ncbi.nlm.nih.gov/pubmed/31057810
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/micronano.2015.43
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