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“Living” Polymerization of Ethylene and 1-Hexene Using Novel Binuclear Pd–Diimine Catalysts
We report the synthesis of two novel binuclear Pd–diimine catalysts and their unique behaviors in initiating “living” polymerization of ethylene and 1-hexene. These two binuclear catalysts, [(N^N)Pd(CH(2))(3)C(O)O(CH(2))(m)O(O)C(CH(2))(3)Pd(N^N)](SbF(6))(2) (3a: m = 4, 3b: m = 6) (N^N≡ArN=C(Me)–(Me)...
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| Publicado no: | Polymers (Basel) |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6432338/ https://ncbi.nlm.nih.gov/pubmed/30970960 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym9070282 |
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