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New Mechanism Proposed for the Base-Catalyzed Urea–Formaldehyde Condensation Reactions: A Theoretical Study
Base-catalyzed urea–formaldehyde condensation reactions were investigated by using a quantum chemistry method. It was found that monomethylolurea or N,N’-dimethylolurea can produce the methyleneurea intermediate (–HN–CO–N=CH(2)) with the catalysis of base. The E1cb (unimolecular elimination of conju...
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| Publicado no: | Polymers (Basel) |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6432254/ https://ncbi.nlm.nih.gov/pubmed/30970883 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym9060203 |
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