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Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins
A mild rhodium-catalyzed annulation of Boc-protected benzamides with diazo compounds via C−C/C−O bond formation has been explored. In the presence of [Cp*RhCl(2)](2), AgSbF(6) and Cs(2)CO(3), Boc-protected benzamides can be effectively annulated to yield isocoumarins in 0.5–2 h.
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| Publicat a: | Molecules |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
MDPI
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6429621/ https://ncbi.nlm.nih.gov/pubmed/30866510 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24050937 |
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