Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment

We present three heterobimetallic complexes containing an isostructural nickel center and a lutetium ion in varying coordination environments. The bidentate (i)Pr(2)PCH(2)NHPh and nonadentate ((i)Pr(2)PCH(2)NHAr)(3)tacn ligands were used to prepare the Lu metalloligands, Lu((i)Pr(2)PCH(2)NPh)(3) (1)...

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Foilsithe in:Chem Sci
Main Authors: Ramirez, Bianca L., Sharma, Prachi, Eisenhart, Reed J., Gagliardi, Laura, Lu, Connie C.
Formáid: Artigo
Teanga:Inglês
Foilsithe: Royal Society of Chemistry 2019
Ábhair:
Chemistry
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6429466/
https://ncbi.nlm.nih.gov/pubmed/30996926
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04712j
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