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Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
There is often a trade-off between mechanical properties (modulus and toughness) and dynamic self-healing. Here we report the design and synthesis of a polymer containing thermodynamically stable whilst kinetically labile coordination complex to address this conundrum. The Zn-Hbimcp (Hbimcp = 2,6-bi...
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| Опубликовано в: : | Nat Commun |
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| Главные авторы: | , , , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
Nature Publishing Group UK
2019
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6411951/ https://ncbi.nlm.nih.gov/pubmed/30858371 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-09130-z |
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