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Substituent Effects of Phenyl Group on Silylene Bridge in Stereospecific Polymerization of Propylene with C(1)-Symmetric Ansa-Silylene(fluorenyl)(amido) Dimethyl Titanium Complexes

A C(1)-symmetric (methylphenyl)silylene-bridged (fluorenyl)(naphthylamido) titanium complex (1) and (diphenyl)silylene-bridged (fluorenyl)(naphthylamido) titanium complex (2) were synthesized and characterized by (1)H NMR, element analysis, and X-ray crystal analysis. The coordination mode of the fl...

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Vydáno v:Polymers (Basel)
Hlavní autoři: Wang, Huajin, Li, Yanqing, Cai, Zhengguo
Médium: Artigo
Jazyk:Inglês
Vydáno: MDPI 2018
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6403971/
https://ncbi.nlm.nih.gov/pubmed/30961000
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym10101075
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