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Total Chemical Synthesis of Human Thyroid-Stimulating Hormone (hTSH) β-Subunit: Application of Arginine-tagged Acetamidomethyl (Acm(R)) Protecting Groups.

The β-subunit of human thyroid stimulating hormone (hTSH) has been synthesized as a single glycoform bearing a chitobiose disaccharide at the native glycosylation site. Key to the successful completion of this synthesis was the introduction of an arginine-tagged acetamidomethyl group, which served t...

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Detalhes bibliográficos
Publicado no:Tetrahedron
Main Authors: Brailsford, John A., Stockdill, Jennifer L., Axelrod*, Abram J., Peterson, Michael T., Vadola, Paul A., Johnston, Eric V., Danishefsky, Samuel J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6402344/
https://ncbi.nlm.nih.gov/pubmed/30853725
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2018.02.067
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