Visualizing the iron atom exchange front in the Fe(II)-catalyzed recrystallization of goethite by atom probe tomography

The autocatalytic redox interaction between aqueous Fe(II) and Fe(III)-(oxyhydr)oxide minerals such as goethite and hematite leads to rapid recrystallization marked, in principle, by an atom exchange (AE) front, according to bulk iron isotopic tracer studies. However, direct evidence for this AE fro...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Taylor, Sandra D., Liu, Jia, Zhang, Xin, Arey, Bruce W., Kovarik, Libor, Schreiber, Daniel K., Perea, Daniel E., Rosso, Kevin M.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2019
Assuntos:
PNAS Plus
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6386708/
https://ncbi.nlm.nih.gov/pubmed/30733289
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1816620116
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