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A hypervalent and cubically coordinated molecular phase of IF(8) predicted at high pressure
Up to now, the maximum coordination number of iodine is seven in neutral iodine heptafluoride (IF(7)) and eight in anionic octafluoride (IF(8)(–)). Here, we explore pressure as a method for realizing new hypercoordinated iodine compounds. First-principles swarm structure calculations have been used...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6385887/ https://ncbi.nlm.nih.gov/pubmed/30881685 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04635b |
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