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Stereoselective synthesis of sulfur-containing β-enaminonitrile derivatives through electrochemical Csp(3)–H bond oxidative functionalization of acetonitrile

Incorporation of nitrile groups into fine chemicals is of particular interest through C(sp(3))–H bonds activation of alkyl nitriles in the synthetic chemistry due to the highly efficient atom economy. However, the direct α-functionalization of alkyl nitriles is usually limited to its enolate chemist...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: He, Tian-Jun, Ye, Zongren, Ke, Zhuofeng, Huang, Jing-Mei
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6381189/
https://ncbi.nlm.nih.gov/pubmed/30783088
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-08762-5
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