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Intermolecular Heck Coupling with Hindered Alkenes Directed by Potassium Carboxylates

Pd(0)-catalyzed Mizoroki-Heck reactions traditionally exhibit poor reactivity with polysubstituted, unbiased alkenes. Intermolecular reactions with simple, all-carbon tetrasubstituted alkenes are unprecedented. Here we report that pendant carboxylic acids, combined with bulky monophospine ligands on...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Huffman, Tucker R., Wu, Yebin, Emmerich, Alexis, Shenvi, Ryan A.
Format: Artigo
Jezik:Inglês
Izdano: 2019
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Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6370521/
https://ncbi.nlm.nih.gov/pubmed/30602064
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813233
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