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Intermolecular Heck Coupling with Hindered Alkenes Directed by Potassium Carboxylates
Pd(0)-catalyzed Mizoroki-Heck reactions traditionally exhibit poor reactivity with polysubstituted, unbiased alkenes. Intermolecular reactions with simple, all-carbon tetrasubstituted alkenes are unprecedented. Here we report that pendant carboxylic acids, combined with bulky monophospine ligands on...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6370521/ https://ncbi.nlm.nih.gov/pubmed/30602064 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201813233 |
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