Association of Halogen Bonding and Hydrogen Bonding in Metal Acetate-Catalyzed Asymmetric Halolactonization

Cooperative activation using halogen bonding and hydrogen bonding works in metal-catalyzed asymmetric halolactonization. The Zn(3)(OAc)(4)-3,3′-bis(aminoimino)binaphthoxide (tri-Zn) complex catalyzes both asymmetric iodolactonization and bromolactonization. Carboxylic acid substrates are converted t...

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Publicado no:iScience
Main Authors: Arai, Takayoshi, Horigane, Kodai, Watanabe, Ohji, Kakino, Junki, Sugiyama, Noriyuki, Makino, Hiroki, Kamei, Yuto, Yabe, Shinnosuke, Yamanaka, Masahiro
Formato: Artigo
Idioma:Inglês
Publicado em: Elsevier 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6365408/
https://ncbi.nlm.nih.gov/pubmed/30731356
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2019.01.029
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