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Cooperative Effects in Weak Interactions: Enhancement of Tetrel Bonds by Intramolecular Hydrogen Bonds

A series of silyl and germanium complexes containing halogen atoms (fluorine and chlorine atoms) and exhibiting tetrel bonds with Lewis bases were analyzed by means of Møller-Plesset computational theory. Binding energies of germanium derivatives were more negative than silicon ones. Amongst the dif...

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Publicado en:Molecules
Main Authors: Trujillo, Cristina, Alkorta, Ibon, Elguero, José, Sánchez-Sanz, Goar
Formato: Artigo
Idioma:Inglês
Publicado: MDPI 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6359400/
https://ncbi.nlm.nih.gov/pubmed/30654469
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24020308
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