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Dual Geometry Schemes in Tetrel Bonds: Complexes between TF(4) (T = Si, Ge, Sn) and Pyridine Derivatives
When an N-base approaches the tetrel atom of TF(4) (T = Si, Ge, Sn) the latter molecule deforms from a tetrahedral structure in the monomer to a trigonal bipyramid. The base can situate itself at either an axial or equatorial position, leading to two different equilibrium geometries. The interaction...
Enregistré dans:
| Publié dans: | Molecules |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
MDPI
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6359171/ https://ncbi.nlm.nih.gov/pubmed/30669688 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24020376 |
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