Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO(2) with epoxides under ambient conditions

A salen based molecular cage, salen@cage, was synthesized and complexed with Co and Al to yield metal–salen molecular cages, Co(ii)@cage, Co(iii)@cage and Al(iii)@cage. These cages were demonstrated to be efficient heterogeneous catalysts for the cycloaddition of CO(2) with styrene oxide, achieving...

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Vydáno v:Chem Sci
Hlavní autoři: Ng, Chee Koon, Toh, Ren Wei, Lin, Ting Ting, Luo, He-Kuan, Hor, T. S. Andy, Wu, Jie
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6357855/
https://ncbi.nlm.nih.gov/pubmed/30809373
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05019h
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