Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters

Group 15 elements in zero oxidation state (P, As, Sb and Bi), also called pnictogens, are rarely used in catalysis due to the difficulties associated in preparing well–structured and stable materials. Here, we report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in z...

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Veröffentlicht in:Nat Commun
Hauptverfasser: Lloret, Vicent, Rivero-Crespo, Miguel Ángel, Vidal-Moya, José Alejandro, Wild, Stefan, Doménech-Carbó, Antonio, Heller, Bettina S. J., Shin, Sunghwan, Steinrück, Hans-Peter, Maier, Florian, Hauke, Frank, Varela, Maria, Hirsch, Andreas, Leyva-Pérez, Antonio, Abellán, Gonzalo
Format: Artigo
Sprache:Inglês
Veröffentlicht: Nature Publishing Group UK 2019
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6355817/
https://ncbi.nlm.nih.gov/pubmed/30705264
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-08063-3
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