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Self-assembled M(12)L(24) nanospheres as a reaction vessel to facilitate a dinuclear Cu(i) catalyzed cyclization reaction

The application of large M(12)L(24) nanospheres allows the pre-concentration of catalysts to reach high local concentrations, facilitating reactions that proceed through dinuclear mechanisms. The mechanism of the copper(i)-catalyzed cyclization of 4-pentynoic acid has been elucidated by means of a d...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Gonell, Sergio, Caumes, Xavier, Orth, Nicole, Ivanović-Burmazović, Ivana, Reek, Joost. N. H.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6354833/
https://ncbi.nlm.nih.gov/pubmed/30809346
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03767a
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