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Alkynylation of graphene via the Sonogashira C–C cross-coupling reaction on fluorographene

We report successful grafting of alkynyl groups onto graphene via the Sonogashira reaction between fluorographene and terminal alkynes. Theoretical calculations revealed that fluorographene can efficiently bind and oxidize the palladium catalyst on electrophilic sites activated by fluorine atoms. Th...

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Vydáno v:Chem Commun (Camb)
Hlavní autoři: Chronopoulos, Demetrios D., Medved’, Miroslav, Błoński, Piotr, Nováček, Zdeněk, Jakubec, Petr, Tomanec, Ondřej, Bakandritsos, Aristides, Novotná, Veronika, Zbořil, Radek, Otyepka, Michal
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6350624/
https://ncbi.nlm.nih.gov/pubmed/30620024
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc08492k
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