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Alkynylation of graphene via the Sonogashira C–C cross-coupling reaction on fluorographene

We report successful grafting of alkynyl groups onto graphene via the Sonogashira reaction between fluorographene and terminal alkynes. Theoretical calculations revealed that fluorographene can efficiently bind and oxidize the palladium catalyst on electrophilic sites activated by fluorine atoms. Th...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Chronopoulos, Demetrios D., Medved’, Miroslav, Błoński, Piotr, Nováček, Zdeněk, Jakubec, Petr, Tomanec, Ondřej, Bakandritsos, Aristides, Novotná, Veronika, Zbořil, Radek, Otyepka, Michal
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6350624/
https://ncbi.nlm.nih.gov/pubmed/30620024
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc08492k
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